Syllabus

Course Code: * Elective - I MTTH-105    Course Name: Advanced Thermodynamics

MODULE NO / UNIT COURSE SYLLABUS CONTENTS OF MODULE NOTES
1 Basic Concepts: Thermodynamics - Zeroth law of thermodynamics – first law of thermodynamics - limitations of first law - Corollaries. Concept of internal energy Transient Flow Analysis - second law of thermodynamics - Corollaries. Concept of entropy- Availability and unavailability – availability function of the closed system - availability of steady flow system Irreversibility.
Thermodynamic Relations: Introduction Thermodynamic Potentials – Maxwell Relations – Specific Heat Relations – Mayer’s relation –General relations for du, dh, ds.
2 Perfect Gases: P.V.T. surface – Equations of state – Real Gas Behavior – Vander Waal’s equation - Generalized compressibility Factor – Energy properties of Real Gases – Vapour pressure – Clausius – Clapeyron Equation – Throttling – Joule – Thompson coefficient.
Non-reactive Mixture of perfect Gases – Governing Laws – Evaluation of properties –Psychrometric Mixture properties and psychrometric chart – Air conditioning processes – Real Gas Mixture.
3 Reactive Gas Mixtures: Combustion: Introduction-– Combustion Reactions – Enthalpy of Formation – Entropy of Formation - Adiabatic flame Temperature -first and second law analysis of reacting systems.
Thermodynamic cycles: Vapor power cycles: Second law analysis of vapor power cycles, cogeneration, Binary vapor cycles, and combined gas vapor power cycles. Gas power cycles: Ideal jet propulsion cyclesSecond law analysis of gas power cycles.
4 Statistical thermodynamics: Statistical interpretations of first and second law and Entropy, Nernst heat theorem.
Kinetic theory of gases: Molecular model, Clausius equation of state, van der waals equation of state, Maxwell Boltzmann velocity distribution
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