Syllabus
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Course Code: CH-502 Course Name: (A) Organometallic chemistry, Inorganic polymers and Quantum mechanics |
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| MODULE NO / UNIT | COURSE SYLLABUS CONTENTS OF MODULE | NOTES |
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| 1 | Organometallic chemistry Definition, classification and nomenclature of organometallic compounds, preparation, properties and bonding of alkyls of Li, Al, Hg and Sn, concept of hapticity of organic ligand, Structure and bonding in metal-ethylenic complexes, Structure of Ferrocene, classification in metal carbonyls, preparation, properties and bonding in mononuclear carbonyls Silicones and Phosphazenes Nomenclature, classification, prepration and uses of silicones, elastomers, polysiloxane copolymers, poly phosphazenes and bonding in triphosphazene. |
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| 2 | Quantum Mechanics-II To show quantum mechanically that position and momentum cannot be predicated simultaneously, Extension of Schrödinger wave equation to two and three dimensional boxes, separation of variables, probability distribution, energy, degeneracy. Qualitative treatment of simple harmonic oscillator model of vibrational motion:Setting up of Schrödinger equation and discussion of solution and wavefunctions.Vibrational energy of diatomic molecules and zero-point energy. Angular momentum: Commutation rules, quantization of square of total angular momentum and z-component. Rigid rotator model of rotation of diatomic molecules. Schrödinger equation,transformation to spherical polar coordinates. Separation of variables. Spherical harmonics. Discussion of solution. |
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